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Immobilization of nano-zero-valent irons by carboxylated cellulose nanocrystals for wastewater remediation

Bangxian Peng, Rusen Zhou, Ying Chen, Song Tu, Yingwu Yin, Liyi Ye

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 6,   Pages 1006-1017 doi: 10.1007/s11705-020-1924-y

Abstract: Here, carboxylated cellulose nanocrystals (CCNC), widely available from renewable biomass resources,In doing so, carboxylated cellulose nanocrystals supporting nano-zero-valent irons (CCNC-nZVI) were obtained

Keywords： carboxylated cellulose nanocrystals     nano-zero-valent irons     magnetic bio-adsorbents     wastewater remediation    

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Dialdehyde cellulose nanocrystal cross-linked chitosan foam with high adsorption capacity for removal

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 7,   Pages 853-866 doi: 10.1007/s11705-022-2256-x

Abstract: The poly(acryloxyethyl trimethylammonium chloride)-graft-dialdehyde cellulose nanocrystals were synthesizedSubsequently, the cationic dialdehyde cellulose nanocrystal cross-linked chitosan nanocomposite foamUnder the optimal ratio of the cationic dialdehyde cellulose nanocrystal/chitosan (w/w) of 12/100, the

Keywords： chitosan foam     cellulose nanocrystals     acid red 134     adsorption    

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Effective and selective adsorption of uranyl ions by porous polyethylenimine-functionalized carboxylated

Juan Shen, Fang Cao, Siqi Liu, Congjun Wang, Rigui Chen, Ke Chen

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 3,   Pages 408-419 doi: 10.1007/s11705-021-2054-x

Abstract: With polyethyleneimine as a functional group, carboxylated chitosan as a matrix, and oxidizing activatedas a nanofiller, this study synthesized a novel environment-friendly polyethylenimine-functionalized carboxylated

Keywords： polyethylenimine     carboxylated chitosan     activated charcoal     uranyl ion     adsorption    

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Sustainable conversion regenerated cellulose into cellulose oleate by sonochemistry

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 8,   Pages 1096-1108 doi: 10.1007/s11705-023-2317-9

Abstract: Derivatization has great potential for the high-value utilization of cellulose by enhancing its processabilityHowever, due to the low reactivity of natural cellulose, it remains challenging to rapidly prepare celluloseThe “cavitation effect” of ultrasound can reduce the particle size and crystalline index of cellulose, which provides a possible method for preparing cellulose derivatives.Herein, a feasible method was proposed for efficiently converting regenerated cellulose to cellulose

Keywords： regenerated cellulose     cellulose oleate     sonochemistry     degree of substitution     thermoplasticity    

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Function-reversible facets enabling SrTiO nanocrystals for improved photocatalytic hydrogen evolution

Frontiers in Energy doi: 10.1007/s11708-023-0894-4

Abstract: It has been widely reported that, for faceted nanocrystals, the two adjacent facets with different bandHerein, by using SrTiO3 nanocrystals enclosed by {023} and {001} facets as a model photocatalyst, this paper proposed a strategy to achieve the full-facets-utilization of the nanocrystals for photocatalyticled to a much-improved activity for photocatalytic hydrogen, in contrast to those SrTiO3 nanocrystals

Keywords： SrTiO3 nanocrystals     crystal facets     photocatalysis     hydrogen evolution    

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Flexible, ultrathin, and multifunctional polypyrrole/cellulose nanofiber composite films with outstanding

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 8,   Pages 1028-1037 doi: 10.1007/s11705-022-2251-2

Abstract: In this study, the flexible, ultrathin, and multifunctional polypyrrole/cellulose nanofiber compositeThe dense sandwich structure and strong interfacial interaction endowed polypyrrole/cellulose nanofibercellulose nanofiber had the highest specific mass capacitance (392.90 F∙g–1) and specificcapacitance (3.32 F∙cm–2) than the electrodes with unmodified and carboxyl functionalized celluloseFurther, the polypyrrole/cellulose nanofiber composite films with sandwich structure had excellent photothermal

Keywords： cellulose nanofiber     electrochemical     photothermal conversion     polypyrrole    

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Graphene-like -BN supported polyhedral NiS/NiS nanocrystals with excellent photocatalytic performance

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 6,   Pages 1537-1549 doi: 10.1007/s11705-021-2094-2

Abstract: Human health is deteriorating due to the effluent containing heavy metal ions and organic dyes. Hence, photoreduction of Cr(VI) to Cr(III) and degradation of rhodamine B (RhB) using a novel photocatalyst is particularly important. In this work, h-BN/NiS2/NiS composites were prepared via a simple solvothermal method and a double Z-scheme heterojunction was constructed for efficiently removing RhB and Cr(VI). The 7 wt-% h-BN/NiS2/NiS composites were characterized via a larger specific surface area (15.12 m2·g–1), stronger light absorption capacity, excellent chemical stability, and high yield of electrons and holes. The experimental result indicated that the photoreduction efficiency of the 7 wt-% h-BN/NiS2/NiS photocatalyst achieved 98.5% for Cr(VI) after 120 min, which was about 3 times higher than that of NiS2/NiS (34%). However, the removal rate of RhB by the 7 wt-% h-BN/NiS2/NiS photocatalyst reached 80%. This is due to the double Z-scheme heterojunction formed between NiS2/NiS and h-BN, which improved the charge separation efficiency and transmission efficiency. Besides, the influence of diverse photogenerated electron and hole scavengers upon the photoreduction of Cr(VI) was studied, the results indicated that graphene-like h-BN promoted transportation of photoinduced charges on the surface of the h-BN/NiS2/NiS photocatalyst via the interfacial effects.

Keywords： graphene-like h-BN     h-BN/NiS2/NiS composites     photocatalysis     Cr(VI) reduction     degradation of RhB    

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Integrating of metal-organic framework UiO-66-NH2 and cellulose nanofibers mat for high-performance adsorption

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 9,   Pages 1387-1398 doi: 10.1007/s11705-022-2154-2

Abstract: In this study, the cellulose nanofibers mat deacetylated from cellulose acetate nanofibers were usedOverall, the approach depicts an efficient model for integrating metal-organic frameworks on cellulose

Keywords： UiO-66-NH2     cellulose nanofibers     rose bengal     adsorption     mechanism    

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Influence of coagulation bath on morphology of cellulose membranes prepared by NMMO method

LU Yangcheng, WU Yingxin

Frontiers of Chemical Science and Engineering 2008, Volume 2, Issue 2,   Pages 204-208 doi: 10.1007/s11705-008-0027-y

Abstract: To control the morphology of cellulose membranes used for separation, they were prepared by the NMMOthe process and mechanism of pore formation in dry membranes were suggested, and the relativity of celluloseBy changing the composition of coagulation baths, the microstructure of cellulose membranes in a dry

Keywords： comparison     NMMO     constant     diameter     process    

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Review on cellulose paper-based electrodes for sustainable batteries with high energy densities

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 8,   Pages 1010-1027 doi: 10.1007/s11705-023-2307-y

Abstract: Cellulose, the main component of paper, represents a unique type of bio-based building blocks featuringThis review focuses on lithium-ion battery application of celluloses with cellulose at different scales, i.e., cellulose microfibers, and nanocellulose, and highlights the new trends in the field.

Keywords： cellulose     paper electrodes     Li-ion batteries     high energy density    

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Influences of spinel type and polymeric surfactants on the size evolution of colloidal magnetic nanocrystals

Tahereh R. BASTAMI,Mohammad H. ENTEZARI,Chiwai KWONG,Shizhang QIAO

Frontiers of Chemical Science and Engineering 2014, Volume 8, Issue 3,   Pages 378-385 doi: 10.1007/s11705-014-1441-y

Abstract: surfactants, PEG and PVP , were used for the preparation of magnetic ferrite MFe O (M= Mn, Fe) colloidal nanocrystals

Keywords： spinel type     polymeric surfactant     size evolution     mangnetic ferrite nanoparticle    

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Bioinspired cellulose-based membranes in oily wastewater treatment

Frontiers of Environmental Science & Engineering 2022, Volume 16, Issue 7, doi: 10.1007/s11783-021-1515-2

Abstract:

• Cellulose-based membrane separates oily wastewater mimicking the living

Keywords： Cellulose     Bioinspired membrane     Superhydrophobic surface     Underwater superoleophobic surface     Oil-water    

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Research progress on low dielectric constant modification of cellulose insulating paper for power transformers

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 8,   Pages 991-1009 doi: 10.1007/s11705-022-2259-7

Abstract: Cellulose insulating paper is the main insulating component of power transformers.Cellulose is used to produce power-transformer insulating papers owing to its excellent electrical propertiesThe dielectric constant of a cellulose insulating paper can be effectively reduced by chemical or physicalFinally, some recommendations for future modified cellulose insulating paper research and applicationsThis paper can provide a reference for further research on low dielectric constant cellulose insulating

Keywords： low dielectric constant     chemical and physical modification     cellulose insulating paper     transformer    

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Nano-copper ions assembled cellulose-based composite with antibacterial activity for biodegradable personal

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10,   Pages 1544-1554 doi: 10.1007/s11705-022-2288-2

Abstract: The current SARS-CoV-2 pandemic has resulted in the widespread use of personal protective equipment, particularly face masks. However, the use of commercial disposable face masks puts great pressure on the environment. In this study, nano-copper ions assembled cotton fabric used in face masks to impart antibacterial activity has been discussed. To produce the nanocomposite, the cotton fabric was modified by sodium chloroacetate after its mercerization, and assembled with bactericidal nano-copper ions (about 10.61 mg·g–1) through electrostatic adsorption. It demonstrated excellent antibacterial activity against Staphylococcus aureus and Escherichia coli because the gaps between fibers in the cotton fabric allow the nano-copper ions to be fully released. Moreover, the antibacterial efficiency was maintained even after 50 washing cycles. Furthermore, the face mask constructed with this novel nanocomposite upper layer exhibited a high particle filtration efficiency (96.08% ± 0.91%) without compromising the air permeability (28.9 min·L–1). This green, economical, facile, and scalable process of depositing nano-copper ions onto modified cotton fibric has great potential to reduce disease transmission, resource consumption, and environmental impact of waste, while also expanding the range of protective fabrics.

Keywords： cellulose-based     nanocomposite     biodegradable antibacterial fabric     nano-copper ions     face masks    

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Simple fabrication of carboxymethyl cellulose and κ-carrageenan composite aerogel with efficient performance

Frontiers of Environmental Science & Engineering 2022, Volume 16, Issue 10, doi: 10.1007/s11783-022-1568-x

Abstract:

● A composite aerogel was simply obtained to remove various fluoroquinolones (FQs).

Keywords： Composite aerogel of carboxymethyl cellulose and κ-carrageenan     Fluoroquinolone antibiotics     Adsorption    

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Title Author Date Type Operation

Immobilization of nano-zero-valent irons by carboxylated cellulose nanocrystals for wastewater remediation

Bangxian Peng, Rusen Zhou, Ying Chen, Song Tu, Yingwu Yin, Liyi Ye

Journal Article

Dialdehyde cellulose nanocrystal cross-linked chitosan foam with high adsorption capacity for removal

Journal Article

Effective and selective adsorption of uranyl ions by porous polyethylenimine-functionalized carboxylated

Juan Shen, Fang Cao, Siqi Liu, Congjun Wang, Rigui Chen, Ke Chen

Journal Article

Sustainable conversion regenerated cellulose into cellulose oleate by sonochemistry

Journal Article

Function-reversible facets enabling SrTiO nanocrystals for improved photocatalytic hydrogen evolution

Journal Article

Flexible, ultrathin, and multifunctional polypyrrole/cellulose nanofiber composite films with outstanding

Journal Article

Graphene-like -BN supported polyhedral NiS/NiS nanocrystals with excellent photocatalytic performance

Journal Article

Integrating of metal-organic framework UiO-66-NH2 and cellulose nanofibers mat for high-performance adsorption

Journal Article

Influence of coagulation bath on morphology of cellulose membranes prepared by NMMO method

LU Yangcheng, WU Yingxin

Journal Article

Review on cellulose paper-based electrodes for sustainable batteries with high energy densities

Journal Article

Influences of spinel type and polymeric surfactants on the size evolution of colloidal magnetic nanocrystals

Tahereh R. BASTAMI,Mohammad H. ENTEZARI,Chiwai KWONG,Shizhang QIAO

Journal Article

Bioinspired cellulose-based membranes in oily wastewater treatment

Journal Article

Research progress on low dielectric constant modification of cellulose insulating paper for power transformers

Journal Article

Nano-copper ions assembled cellulose-based composite with antibacterial activity for biodegradable personal

Journal Article

Simple fabrication of carboxymethyl cellulose and κ-carrageenan composite aerogel with efficient performance

Journal Article